Anwendung differenzierter Untersuchungsmethoden zur Sedimentbewertung

The aquatic sediments have special significance as habitats of species-rich biocoenoses and as the place where manifold transformation processes occur. Because of their high potential for accumulation of contaminants, sediments are particularly sensitive to anthropogenic impacts, which may disturb the natural state of sediments. In order to protect the aquatic life community, such impacts must be identified, assessed, and the chemical causes of toxic effects must be found. Since the end of the 1980s, the interest for a possibly comprehensive assessment of sediments has increased. This problem can be tackled only by an integrated approach, which combines the detection of toxicity under standardized laboratory conditions with chemical data and biologicalin situ studies into a holistic view. The information value of the results depends essentially on the selection of a diversity of test methods, which are able to indicate contaminant effects differentially. This paper presents results from a comprehensive test approach, which integrates standardized methods (DIN) with pore waters and eluates, as well as tests using the whole sediment. To cover a wider variety of contaminants in the sediment, solvent extracts and fractions thereof were also examined by different bioassays. Chemical analyses examined the structural parameters and identified priority contaminants. Non-target screening could detect a variety of further substances and substance classes. The model organisms of the bioassays responded very differentially and sometimes very intensively to the contaminants in the various investigation media. Especially in sediment extracts, some fractions, and consequently also substances and groups of substances, proved to be particularly toxic. It could be shown that the selected chemical, ecotoxicological, and biological study methods contribute to a holistic assessment. Further, possibly very sensitive bioassays and benthos-biological parameters should be examined aiming to optimize the very wide battery of tests.     

Optimal management of renewable resources with growing demand and stock externalities

In an equilibrium framework, optimal management of renewable resources in the presence of growing demand or externalities leads to steady states that differ from those characterized by rate of interest equals rate of change in growth plus rate of change in prices. Measures to reach an optimum with externalities other than direct controls are found to be critically mediated by the costs of harvesting.     

Occurrence and temporal variations of TMDD in the river Rhine,Germany

Background, aim, and scope

The chemical substance 2,4,7,9-tetramethyl-5-decyne-4,7-diol (TMDD) is a non-ionic surfactant used as an industrial defoaming agent and in various other applications. Its commercial name is Surynol 104® and the related ethoxylates are also available as Surfynol® 420, 440, 465 and 485 which are characterized by different grades of ethoxylation of TMDD at both hydroxyl functional groups. TMDD and its ethoxylates offer several advantages in waterborne industrial applications in coatings, inks, adhesives as well as in paper industries. TMDD and its ethoxylates can be expected to reach the aquatic environment due its widespread use and its physico-chemical properties. TMDD has previously been detected in several rivers of Germany with concentrations up to 2.5?µg/L. In the United States, TMDD was also detected in drinking water. However, detailed studies about its presence and distribution in the aquatic environment have not been carried out so far. The aim of the present study was the analysis of the spatial and temporal concentration variations of TMDD in the river Rhine at the Rheingütestation Worms (443.3 km). Moreover, the transported load in the Rhine was investigated during two entire days and 7 weeks between November 2007 and January 2008.

Materials and methods

The sampling was carried out at three different sampling points across the river. Sampling point MWL1 is located in the left part of the river, MWL2 in the middle part, and MWL4 in the right part. One more sampling site (MWL3) was run by the monitoring station until the end of 2006, but was put out of service due to financial constrains. The water at the left side of the river Rhine (MWL1) is influenced by sewage from a big chemical plant in Ludwigshafen and by the sewage water from this city. The water at the right side of the river Rhine (MWL4) is largely composed of the water inflow from river Neckar, discharging into Rhine 14.9 km upstream from the sampling point and of communal and industrial wastewater from the city Mannheim. The water from the middle of the river (MWL2) is largely composed of water from the upper Rhine. Water samples were collected in 1-L bottles by an automatic sampler. The water samples were concentrated by use of solid-phase extraction (SPE) using Bond Elut PPL cartridges and quantified by use of gas chromatography-mass spectrometry (GC-MS). The quantification was carried out with the internal standard method. Based on these results, concentration variations were determined for the day profiles and week profiles. The total number of analyzed samples was 219.

Results

The results of this study provide information on the temporal concentration variability of TMDD in river Rhine in a cross section at one particular sampling point (443.3 km). TMDD was detected in all analyzed water samples at high concentrations. The mean concentrations during the 2 days were 314 ng/L in MWL1, 246 ng/L in MWL2, and 286 ng/L in MWL4. The variation of concentrations was low in the day profiles. In the week profiles, a trend of increasing TMDD concentrations was detected particularly in January 2008, when TMDD concentrations reached values up to 1,330 ng/L in MWL1. The mean TMDD concentrations during the week profiles were 540 ng/L in MWL1, 484 ng/L in MWL2, and 576 ng/L in MWL4. The loads of TMDD were also determined and revealed to be comparable in all three sections of the river. The chemical plant located at the left side of the Rhine is not contributing additional TMDD to the river. The load of TMDD has been determined to be 62.8 kg/d on average during the entire period. By extrapolation of data obtained from seven week profiles the annual load was calculated to 23 t/a.

Discussion

The permanent high TMDD concentrations during the investigation period indicate an almost constant discharge of TMDD into the river. This observation argues for effluents of municipal wastewater treatment plants as the most likely source of TMDD in the river. Another possible source might be the degradation of ethoxylates of TMDD (Surfynol® series 400), in the WWTPs under formation of TMDD followed by discharge into the river. TMDD has to be considered as a high-production-volume (HPV) chemical based on the high concentrations found in this study. In the United States, TMDD is already in the list of HPV chemicals from the Environmental Protection Agency (EPA). However, the amount of TMDD production in Europe is unknown so far and also the biodegradation rates of TMDD in WWTPs have not been investigated.

Conclusions

TMDD was found in high concentrations during the entire sampling period in the Rhine river at the three sampling points. During the sampling period, TMDD concentrations remained constant in each part of the river. These results show that TMDD is uniformly distributed in the water collected at three sampling points located across the river. ‘Waves’ of exceptionally high concentrations of TMDD could not be detected during the sampling period. These results indicate that the effluents of WWTPs have to be considered as the most important sources of TMDD in river Rhine.

Recommendations and perspectives

Based also on the occurrence of TMDD in different surface waters of Germany with concentrations up to 2,500 ng/L and its presence in drinking water in the USA, more detailed investigations regarding its sources and distribution in the aquatic environment are required. Moreover, the knowledge with respect to its ecotoxicity and its biodegradation pathway is scarce and has to be gained in more detail. Further research is necessary to investigate the rate of elimination of TMDD in municipal and industrial wastewater treatment plants in order to clarify the degradation rate of TMDD and to determine to which extent effluents of WWTPs contribute to the input of TMDD into surface waters. Supplementary studies are needed to clarify whether the ethoxylates of TMDD (known as Surfynol 400® series) are hydrolyzed in the aquatic environment resulting in formation of TMDD similar to the well known cleavage of nonylphenol ethoxylates into nonylphenols. The stability of TMDD under anaerobic conditions in groundwater is also unknown and should be studied.

     

Integrating contributing areas and indexing phosphorus loss from agricultural watersheds

Most states in the USA have adopted P Indexing to guide P-based management of agricultural fields by identifying the relative risk of P loss at farm and watershed scales. To a large extent, this risk is based on hydrologic principles that frequently occurring storms can initiate surface runoff from fields. Once initiated, this hydrological pathway has a high potential to transport P to the stream. In regions where hydrologically active areas of watersheds vary in time and space, surface runoff generation by "saturation excess" has been linked to distance from stream, with larger events resulting in larger contributing distances. Thus, storm-return period and P loss from a 39.5-ha mixed-land-use watershed in Pennsylvania was evaluated to relate return-period thresholds and distances contributing P to streams. Of 248 storm flows between 1997 and 2006, 93% had a return period of 1 yr, contributing 47% of total P (TP) export, while the largest two storms (10-yr return period) accounted for 23% of TP export. Contributing distance thresholds for the watershed were determined (50-150 m) for a range of storm-return periods (1-10 yr) from hydrograph analysis. By modifying storm-return period thresholds in the P Index and thereby contributing distance, it is possible to account for greater risk of P loss during large storms. For instance, increasing return period threshold from 1 (current P indices) to 5 yr, which accounted for 67% of TP export, increased the P-management restricted area from 20 to 58% of the watershed. An increase in impacted area relative to a decreased risk of P loss creates a management-policy dilemma that cannot be ignored.     

Hydrogeological relationships of sandy deposits: modeling of two-dimensional unsaturated water and pesticide transport

Prediction of the movement of water and solutes in the vadose zone requires information on the distribution of spatial trends and heterogeneities in porous media. The present study describes different lithofacies origination mainly from glaciofluvial deposits. Among different lithofacies, hydrological relationships were investigated. By means of a two-dimensional hydrological model it was evaluated how the flow of water and leaching of metribuzin (4-amino-6-tert-butyl-4,5-dihydro-3-methylthio-1,2,4-triazin-5-one) was affected. Two selected large outcrop sections consisting of glacial outwash deposits were used in the modeling study. Eleven different lithofacies were distinguished and described in terms of texture distribution, sorting, bedding style, and external boundaries based on excavated soil profiles from 27 locations representing seven predominantly sandy landforms in Denmark. Undisturbed soil columns were sampled from each of the lithofacies and brought to the laboratory to be analyzed. With respect to their soil hydraulic properties, the different lithofacies formed four different hydrofacies having relatively homogeneous, hydrogeological properties. Two large outcrop sections from one of the locations (a gravel pit) located near the terminal moraine of the former Weichsel glacier were used for the HYDRUS-2D modeling. Modeling results revealed that the spatial distribution of sedimentary bodies affected water flow and the leaching of metribuzin.